関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Tributylvinyltin | HCID 81998 | — |
| 反応物 | Ethyl 3-(bromophenyl)acetate | HCID 11470552 | — |
| 触媒 | HCID 178418397 | HCID 178418397 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Ethyl 2-(3-vinylphenyl)acetate | HCID 11687033 | — |
反応手順
A mixture of 1.0 mmol of ethyl 3-bromophenylacetate, 1.5 mmol of vinyltributyltin, and 0.1 mmol of Pd(PPh3)4 in 4 mL DMF was stirred and heated at 90° C. for 1-16 h. Chromatography provided ethyl 3-vinylphenylacetate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05731432 |
|---|
| 出典データセット | uspto-grants-1998_03 |
|---|
| ORD ID | ord-22f4a8336221412198601584d84cd4b1 |
|---|
| 出典メモ | uspto-grants-1998_03 |
|---|
