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Benzene, ((2-bromoethoxy)methyl)- → [(S)-5-(2-Benzyloxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-carbamic acid tert-butyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene, ((2-bromoethoxy)methyl)- | HCID 73833 | — |
| 反応物 | ((S)-6-Oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-carbamic acid tert-butyl ester | HCID 58972520 | — |
| 生成物 | [(S)-5-(2-Benzyloxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-carbamic acid tert-butyl ester | HCID 58972521 | — |
反応手順
Using ((S)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-carbamic acid tert-butyl ester and benzyl 2-bromoethyl ether, the title compound was prepared in the same manner as described for example 1a. White crystals, mp. 132-134° C. (84%). MS: m/e=459(M+H+), mp 133° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07425551B2 |
| 出典データセット | uspto-grants-2008_09 |
| ORD ID | ord-b10b5b2464b44662a61ec1b7d73d2581 |
| 出典メモ | uspto-grants-2008_09 |