化工社化工社 化学情報印刷レポート · 研究参考用
Nitrobenzene → Dimethyl phenanthrene-3,4-dicarboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Nitrobenzene | HCID 7416 | — |
| 反応物 | 2-Vinylnaphthalene | HCID 13230 | — |
| 反応物 | HCID 86613298 | HCID 86613298 | — |
| 生成物 | Dimethyl phenanthrene-3,4-dicarboxylate | HCID 15075419 | — |
反応手順
A solution of 65 mmol of 2-vinylnaphthalene and 68 mmol of methyl acetylene-dicarboxylate in 200 ml of nitrobenzene is maintained at reflux for 14 hours. After distillation of the solvent, the reaction medium is chromatographed on silica (eluent: CH2Cl2) in order to obtain the expected product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06300340B1 |
| 出典データセット | uspto-grants-2001_10 |
| ORD ID | ord-f13ee31e844043908b56df1cb1976e0b |
| 出典メモ | uspto-grants-2001_10 |