関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dicyclopentadiene | HCID 6492 | — |
| 反応物 | 4-Penten-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)- | HCID 328870 | — |
| 生成物 | 8-(2,2,2-Trifluoro-1-trifluoromethyl-1-hydroxyethyl)tetracyclo[4.4.0.12,5.17,10]dodec-3-ene | HCID 20617087 | 22.2% |
反応手順
A 500 ml autoclave was charged with 230 g of 1,1-bis(trifluoromethyl)-3-butenol, 73 g of dicyclopentadiene, and 0.15 g of 2,6-di-t-butylparacresol, and the mixture was heated at 190° C. for 12 hours. The reaction solution was cooled to room temperature and purified by distillation to obtain 40 g of 8-(2,2,2-trifluoro-1-trifluoromethyl-1-hydroxyethyl)tetracyclo[4.4.0.12,5.17,10]dodec-3-ene of the following formula (13).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06800414B2 |
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| 出典データセット | uspto-grants-2004_10 |
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| ORD ID | ord-c5a8c281d9034da7adddb676a06667da |
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| 出典メモ | uspto-grants-2004_10 |
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