化工社化工社 化学情報印刷レポート · 研究参考用
p-n-Octadecyloxybenzoic acid → 4-(trans-3-Decenyloxy)-benzoic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | p-n-Octadecyloxybenzoic acid | HCID 139993 | — |
| 反応物 | Lithium hydroxide, monohydrate | HCID 168937 | — |
| 反応物 | Methyl-4-(trans-3-decenyloxy)-benzoate | HCID 18521096 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 4-(trans-3-Decenyloxy)-benzoic acid | HCID 18521103 | — |
反応手順
Ester 35h (600 mg, 2.07 mmol), and lithium hydroxide monohydrate (867 mg, 20.7 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 500 mg (87%) of a white powder which was not quite pure (95%). The product was used without further purification.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06569504B1 |
| 出典データセット | uspto-grants-2003_05 |
| ORD ID | ord-d8c3667c163749e7a921df5f12e71ed3 |
| 出典メモ | uspto-grants-2003_05 |