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Styrene → p-Tert-butoxystyrene styrene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | 1-(Tert-butoxy)-4-ethenylbenzene | HCID 577531 | — |
| 生成物 | p-Tert-butoxystyrene styrene | HCID 69102216 | — |
反応手順
The same reaction and after-treatment using 81.1 g (0.46 mole) of p-tert-butoxystyrene and 4.6 g (0.04 mole) of styrene as described in Production Example 4-(1) were conducted to give 80.5 g of poly(p-tert-butoxystyrene/styrene) as white powders. Then, the polymer was subjected to the same reaction and after-treatment as described in Production Example 9-(1) to give 44.0 g of poly(p-hydroxystyrene/styrene) as white powders. A ratio of p-hydroxystyrene unit and styrene unit was about 92:8 by 1HNMR. Mw: about 15500, Mw/Mn: 1.08 (GPC method: polystyrene as standard).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06656660B1 |
| 出典データセット | uspto-grants-2003_12 |
| ORD ID | ord-12e6d8d90c484058b50236fc8c75e009 |
| 出典メモ | uspto-grants-2003_12 |