関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrazinecarboxylic acid, ethyl ester | HCID 20064 | — |
| 反応物 | 3-Chloro-1-methyl-1,2-dihydroquinoxalin-2-one | HCID 1471088 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | Ethyl-3-(1-methyl-2-oxo(2H)quinoxalin-3-yl)carbazate | HCID 13192930 | — |
反応手順
A solution of 152 g. (0.78 m.) of 3-chloro-1-methyl-1H-quinoxalin-2-one, 116 g. (1.1 m.) of ethyl carbazate and 1 l. of acetonitrile is refluxed for 16 hours. The mixture is cooled to 9° C. and the product collected by filtration and used directly for cyclization.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04400382 |
|---|
| 出典データセット | uspto-grants-1983_08 |
|---|
| ORD ID | ord-524da58c8bf04d29a4c2c0c994e287c1 |
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| 出典メモ | uspto-grants-1983_08 |
|---|
