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1,3-Dithiolane → Ethyl acetate hexane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3-Dithiolane | HCID 20970 | — |
| 反応物 | 2-Aminomethylquinoline | HCID 3014378 | — |
| 反応物 | Z-Leu-Abu-COOEt | HCID 101658032 | — |
| 生成物 | Ethyl acetate hexane | HCID 21226206 | 16% |
反応手順
This compound was prepared from 1,3-dithiolane derivative of Z-Leu-Abu-COOEt and 2-aminomethylquinoline by the procedure described in Example 38, and purified by column chromatography using AcOEt/hexane 2:1 (16% yield). Yellow solid, single spot on TLC, Rf =0.27 (AcOEt/hexane 2:1), mp 135°-138° C. 1H NMR (CDCl3) ok, MS (FAB) m/e=519 (M+1). Anal: calcd. for C29H34N4O5, 518; C, 67.16; H, 6.60; N, 10.80. Found, C, 66.89; H, 6.68; N, 10.61.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05514694 |
| 出典データセット | uspto-grants-1996_05 |
| ORD ID | ord-662cdbc14dcd4809ad99d32ccf3e66e0 |
| 出典メモ | uspto-grants-1996_05 |