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Pyridine → Benzoyloxymethylpyridinium chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Chloromethyl benzoate | HCID 79257 | — |
| 反応物 | Potassium Bromide | HCID 253877 | — |
| 生成物 | Benzoyloxymethylpyridinium chloride | HCID 12602695 | — |
反応手順
A mixture containing 0.79 g (0.01 mol) pyridine and 1.7 g (0.01 mol) chloromethyl benzoate was allowed to react at ambient temperature for 24 hr. Trituration in anhydrous ether followed by filtration under nitrogen gave 1.2 g (0.005 mol), 50%, 29, mp 197°-199° (dec); ir (KBr) 3440, 3020, 1710, 1610, 1475, 1265, 1150, 1085, 870 and 700 cm-1 ; pmr (D2O) δ 7.0-10.0 (m, 10H) and 6.6 (s, 2H) ppm.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04727151 |
| 出典データセット | uspto-grants-1988_02 |
| ORD ID | ord-d6803dbfbc1e4f0fbfab242ee261a3d9 |
| 出典メモ | uspto-grants-1988_02 |