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4,4'-Dimethoxydiphenylamine → 4-Methoxy-N-(4-methoxyphenyl)-N-phenylaniline
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4,4'-Dimethoxydiphenylamine | HCID 7571 | — |
| 反応物 | Iodobenzene | HCID 11575 | — |
| 反応物 | sodium 2-methylpropan-2-olate | HCID 178418730 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 生成物 | 4-Methoxy-N-(4-methoxyphenyl)-N-phenylaniline | HCID 10543043 | — |
反応手順
1.00 g (4.46 mmols) of N,N-di(4-methoxyphenyl)amine (31a), 1.00 g (4.90 mmols) of iodobenzene (32a), 0.502 g (5.23 mmols) of t-BuONa and 0.010 g (0.044 mmols) of Pd(CH3COO)2 were dissolved in anhydrous xylene, and while refluxing the solution in an atmosphere of nitrogen, 1.0 ml of 0.237 M of P(But)3 was further dropped, followed by refluxing for 4 hours.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06979746B2 |
| 出典データセット | uspto-grants-2005_12 |
| ORD ID | ord-1c9b7ed7850a4341956aa0d649b0ad8a |
| 出典メモ | uspto-grants-2005_12 |