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Sodium Hydroxide → 4-Carboxyphenylboronic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Tolylboronic acid | HCID 79799 | — |
| 反応物 | Potassium Permanganate | HCID 516875 | — |
| 生成物 | 4-Carboxyphenylboronic Acid | HCID 312183 | — |
反応手順
To a solution of 4-methylphenylboronic acid (34 g, 0.25 mol) in aqueous sodium hydroxide (0.5 N, 1000 mL) was added potassium permanganate (83 g, 0.53 mol) while keeping the temperature at 35-40° C. After the addition the reaction was filtered and the filtrate acidified with concentrated hydrochloric acid (65 mL). The product was filtered off. A yield of 29.6 g was obtained. M.p. 228° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06706749B2 |
| 出典データセット | uspto-grants-2004_03 |
| ORD ID | ord-85361952dc384526833644ea8fd303a8 |
| 出典メモ | uspto-grants-2004_03 |