化工社化工社 化学情報印刷レポート · 研究参考用
Acetone → HCID 57419464、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetone | HCID 180 | — |
| 反応物 | Dimethyl Sulfate | HCID 6497 | — |
| 反応物 | 3,5-Diiodosalicylic acid | HCID 8631 | — |
| 生成物 | HCID 57419464 | HCID 57419464 | — |
反応手順
A mixture of 2-hydroxy-3,5-diiodobenzoic acid (3.9 g, 10.0 mmol) potassium carbonate (4.15 g, 30.0 mmol) and dimethyl sulfate (2.77 g, 22.0 mmol) in acetone (33 ml) was heated at reflux for 16 h, cooled and concentrated. The residue was dissolved in EtOAc and washed with water, brine, dried (Na2SO4), filtered and concentrated to give an off-white solid (4.2 g, quantitative yield).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09095590B2 |
| 出典データセット | uspto-grants-2015_08 |
| ORD ID | ord-e6ee1f4f5e034f97afe232c2fb260e3c |
| 出典メモ | uspto-grants-2015_08 |