化工社化工社 化学情報印刷レポート · 研究参考用
Dimethylformamide → 3,4,5-Triacetoxybenzoyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | Benzoic acid, 3,4,5-tris(acetyloxy)- | HCID 95088 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 3,4,5-Triacetoxybenzoyl chloride | HCID 155506 | — |
反応手順
3,4,5-Triacetoxybenzoic acid (296.23 g, 1 mol) was slurried in a 2 L flask in CH2Cl2 (1.0 L), and oxalyl chloride (113 mL, 1.3 mol) as added, followed by slow, dropwise addition of N,N-dimethylformamide (1.5 mL). After 2 hours at RT, gas evolution had ceased, and 3,4,5-triacetoxybenzoyl chloride was isolated by evaporation under reduced pressure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05244763 |
| 出典データセット | uspto-grants-1993_09 |
| ORD ID | ord-6fca121f54ad4dbeb09f154726606a7f |
| 出典メモ | uspto-grants-1993_09 |