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Lithium azide → 1-Azido-1-(5-chloro-2-pyridyl)-2-(1H-imidazol-1-yl)ethane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Lithium azide | HCID 88163 | — |
| 反応物 | 1-chloro-(5-chloro-2-pyridyl)-2-(1H-imidazol-1-yl)ethane | HCID 19959423 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 1-Azido-1-(5-chloro-2-pyridyl)-2-(1H-imidazol-1-yl)ethane | HCID 19959415 | — |
反応手順
0.92 g of 1-chloro-(5-chloro-2-pyridyl)-2-(1H-imidazol-1-yl)ethane are added under argon to a solution of 0.37 g of lithium azide in 2 ml of dry dimethylformamide and the reaction mixture is stirred at 60° for 18 hours. Working up according to process A (see Example 1) gives the substance as a yellowish oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05622982 |
| 出典データセット | uspto-grants-1997_04 |
| ORD ID | ord-a1872d4c2faa42f194f06d6f8cbe80f7 |
| 出典メモ | uspto-grants-1997_04 |