化工社化工社 化学情報印刷レポート · 研究参考用
Sulfuric Acid → 1,4-Anhydrohexitol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sulfuric Acid | HCID 1118 | — |
| 反応物 | Sorbitol | HCID 5780 | — |
| 反応物 | L-Sorbitol | HCID 82170 | — |
| 反応物 | Sodium borohydride | HCID 4311764 | — |
| 反応物 | 1,4-Sorbitan | HCID 10953859 | — |
| 反応物 | GlyTouCan:G06186NU | HCID 10954115 | — |
| 反応物 | L-enantiomer | HCID 11391247 | — |
| 反応物 | GlyTouCan:G26655QK | HCID 67592081 | — |
| 生成物 | 1,4-Anhydrohexitol | HCID 552087 | — |
反応手順
1,4-Anhydro-D-glucitol may be prepared using the procedure disclosed in Acta Chem. Scand., B35, 441-449 (1981), whereby D-sorbitol is heated with an aqueous mineral acid such as sulfuric acid. The L-enantiomer, 1,4-anhydro-L-glucitol, may be prepared from L-glucitol by an analogous procedure. L-glucitol may be prepared by sodium borohydride reduction of L-glucose. The D and L enantiomers may simply be combined to form a 1,4-anhydro-DL-glucitol mixture.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06007848 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-12288f4f8e3745ad93e985bd6c12d4c8 |
| 出典メモ | uspto-grants-1999_12 |