化工社化工社 化学情報印刷レポート · 研究参考用
HRID 61329作成日：2026年10月24日
[1-(1,2-Dimethyl-propyl)-4-methyl-cyclohex-3-enyl]-methanol → 4-(1,2-Dimethyl-propyl)-1-methyl-2-oxa-bicyclo[2.2.2]octane
https://huagongshe.com/ja/reaction/61329
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | [1-(1,2-Dimethyl-propyl)-4-methyl-cyclohex-3-enyl]-methanol | HCID 89705124 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 4-(1,2-Dimethyl-propyl)-1-methyl-2-oxa-bicyclo[2.2.2]octane | HCID 89705424 | 54.5% |
反応手順
[1-(1,2-Dimethyl-propyl)-4-methyl-cyclohex-3-enyl]-methanol (268 g, obtained as detailed above), MSA (10 g), and toluene (300 mL) were charged to a 2 L reaction flask, heated to 60° C., and aged for 12 hours. The reaction mixture was cooled, washed with saturated sodium carbonate solution, and distilled to provide 4-(1,2-dimethyl-propyl)-1-methyl-2-oxa-bicyclo[2.2.2]octane (146 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09441185B2 |
|---|
| 出典データセット | uspto-grants-2016_09 |
|---|
| ORD ID | ord-5ac573a873e940709e164533c4b7567b |
|---|
| 出典メモ | uspto-grants-2016_09 |
|---|
