化工社化工社 化学情報印刷レポート · 研究参考用
1,3-Butadiene → 1-Nitronaphthalene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3-Butadiene | HCID 7845 | — |
| 反応物 | 5-Nitro-1,4,4a,9a-tetrahydroanthraquinone | HCID 10868940 | — |
| 反応物 | 5-Nitronaphthalene-1,4-dione | HCID 12336402 | — |
| 生成物 | 1-Nitronaphthalene | HCID 6849 | — |
| 生成物 | 5-Nitronaphthalene-1,4-dione | HCID 12336402 | — |
反応手順
The starting 5-nitro-1,4,4a,9a-tetrahydroanthraquinone of formula II is known and can be prepared e.g. by Diels-Alder reaction of butadiene with 5-nitro-1,4-naphthoquinone. 5-Nitro-1,4-naphthoquinone can in turn be obtained e.g. by electrolytic oxidation of 1-nitronaphthalene or by nitration of 1,4-naphthoquinone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04770818 |
| 出典データセット | uspto-grants-1988_09 |
| ORD ID | ord-5205d532e0a246ef93f0e92f5ba5a842 |
| 出典メモ | uspto-grants-1988_09 |