化工社化工社 化学情報印刷レポート · 研究参考用
Diethyl Malonate → Diethyl pentafluorobenzylmalonate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethyl Malonate | HCID 7761 | — |
| 反応物 | Pentafluorobenzaldehyde | HCID 69558 | — |
| 生成物 | Diethyl pentafluorobenzylmalonate | HCID 88651511 | 69% |
反応手順
9 g of pentafluorobenzaldehyde are condensed on 7 g of diethyl malonate in accordance with the process described in Organic Synthesis vol. III, page 377. 10 g (69%) of diethyl pentafluorobenzylmalonate are obtained which is hydrogenated at ordinary pressure in the presence of palladium on charcoal into diethyl pentafluorobenzylmalonate (92%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04738803 |
| 出典データセット | uspto-grants-1988_04 |
| ORD ID | ord-16b1b55501134601a9cbffcc03de0787 |
| 出典メモ | uspto-grants-1988_04 |