関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethyl Carbonate | HCID 12021 | — |
| 反応物 | Phenyl chloroformate | HCID 15891 | — |
| 触媒 | Tbpb | HCID 10092649 | — |
| 生成物 | Diphenyl carbonate | HCID 7597 | 98% |
反応手順
A mixture of 7.83 g (0.05 mole) of phenyl chloroformate, 2.48 g (0.0275 mole) of dimethyl carbonate, and 0.85 g of TBPB was heated at 150° C. under a reflux condenser for 4 hours when all gas evolution had ceased. Distillation of the reaction mixture gave 5.25 g (98 percent yield based on chloroformate) of diphenyl carbonate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04612386 |
|---|
| 出典データセット | uspto-grants-1986_09 |
|---|
| ORD ID | ord-bc5acf575b5c44f6967b29f0bee19519 |
|---|
| 出典メモ | uspto-grants-1986_09 |
|---|
