化工社化工社 化学情報印刷レポート · 研究参考用
Allyl bromide → N-[4-(Allylsulfonyl)phenyl]acetamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl bromide | HCID 7841 | — |
| 反応物 | 4-(Acetylamino)benzenesulfinic acid | HCID 412150 | — |
| 反応物 | Sodium Bicarbonate | HCID 516892 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N-[4-(Allylsulfonyl)phenyl]acetamide | HCID 20375362 | — |
反応手順
50 Parts of p-acetylaminophenylsulfinic acid and 25 parts of sodium hydrogen carbonate are suspended in 300 parts of water. While stirring intensely 36 parts of allyl bromide is dripped in within 3 hours at 50° to 60° C. Stirring is continued for another 4 hours at 60° C. 45 parts of p-allylsulfonylacetanilide is obtained with a melting point of 116° to 118° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04129563 |
| 出典データセット | uspto-grants-1978_12 |
| ORD ID | ord-b7eadcc681184887b4d6356783e873da |
| 出典メモ | uspto-grants-1978_12 |