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HRID 7389作成日:2026年10月24日

1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(beta-D-glucopyranosyloxy)-5-methyl-1H-pyrazole → 2-(5-Methyl-pyrazol-1-YL)-ethanol

https://huagongshe.com/ja/reaction/7389

反応式

関与物質

役割名称HCID仕込み量
反応物1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(beta-D-glucopyranosyloxy)-5-methyl-1H-pyrazoleHCID 69133733—
触媒HCID 178418390HCID 178418390—
溶媒EthanolHCID 702—
生成物2-(5-Methyl-pyrazol-1-YL)-ethanolHCID 12360320372.5%

反応手順

To a solution of 1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-5-methyl-1H-pyrazole (0.012 g) in ethanol (2 mL) was added a catalytic amount of 10% palladium-carbon powder, and the mixture was stirred at room temperature under a hydrogen atmosphere for 30 minutes. Insoluble materials were removed by filtration, and the solvent was removed under reduced pressure to give 4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-1-(2-hydroxyethyl-5-methyl-1H-pyrazole (0.011 g).

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07087579B2
出典データセットuspto-grants-2006_08
ORD IDord-061bca7ca0d24355a6d61c73b9464cfc
出典メモuspto-grants-2006_08