関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Methyl chloroacetate | HCID 7295 | — |
| 反応物 | (Trimethylsilyl)imidazole | HCID 28925 | — |
| 生成物 | 1,3-Bis(2-methoxy-2-oxoethyl)-1H-imidazol-3-ium chloride | HCID 86762740 | 99.7% |
反応手順
Methyl chloroacetate (2; 29.8 mL, 338.6 mmol, 2.0 eq) was added drop-wise to 1-(trimethylsilyl)-1H-imidazole (8; 25.0 mL, 169.3 mmol). The mixture was heated at 60° C. for 24 hours. The mixture was cooled to room temperature, washed with Et2O (3×500 mL) and dried in vacuo yielding 9 (41.97 g, 168.8 mmol, 99.7%) as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08835650B1 |
|---|
| 出典データセット | uspto-grants-2014_09 |
|---|
| ORD ID | ord-f0327e03632d45c29e19be139b70e8eb |
|---|
| 出典メモ | uspto-grants-2014_09 |
|---|
