4-Pyridinecarboxaldehyde → HCID 12161434、化合物

関与物質

反応手順

2,5-bis(4-pyridylhydroxymethyl)selenophene was prepared by a reaction of 9.04 mL (0.09 mol) 4-pyrdinecarboxaldehyde with 3.5 mL (0.04 mol) selenophene by a procedure similar to that described above. The 2,5-bis(4-pyridylhydroxymethyl)selenophene was obtained in 20% yield. 1H NMR (DMSO-d6) δ 8.48 (d, J=3.4 Hz, 4H), 7.36 (d, J=3.4 Hz, 2H), 7 6.87 (s, 2H), 6.93 (s, 2H), 6.44 (brs, 2H), 5.82 (s, 2H); HRMS (FAB) (M+) calcd. for C16H15O2N2Se: 347.0299; found, 347.0301.

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