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Chlorodiisopropylphosphine → N1-(2-isopropyl-6-methylphenyl)-N2-(diisopropyl-phosphino)-4-methylbenzamidine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorodiisopropylphosphine | HCID 538967 | — |
| 反応物 | Butyllithium | HCID 178418339 | — |
| 反応物 | HCID 178425631 | HCID 178425631 | — |
| 生成物 | N1-(2-isopropyl-6-methylphenyl)-N2-(diisopropyl-phosphino)-4-methylbenzamidine | HCID 178425661 | — |
反応手順
Procedure as described for NP Amidine I using the following amounts: 1.33 g of N1-(2-isopropyl-6-methylphenyl)-4-methylbenzamidine (Amidine V, 5.0 mmol), 2.50 mL of 2.0 M butyllithium (5.0 mmol), 0.80 mL chlorodiisopropylphosphine (5.0 mmol). After filtration to remove lithium chloride and removal of solvent, a yellow semi-solid was isolated (1.86 g, 97%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09283555B2 |
| 出典データセット | uspto-grants-2016_03 |
| ORD ID | ord-0dc94fc71bc24b18b415f2c8fc3d938c |
| 出典メモ | uspto-grants-2016_03 |