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HCID 11430생성일: 2026년 10월 23일

탄산 칼륨

디칼륨탄산 · 조제탄산칼륨 · 타르타르의염 · 알칼리 · 탄산칼륨 · 탄산,디칼륨염 · 탄산칼리 · 포타슘카보네이트

https://huagongshe.com/ko/chemical/11430

탄산 칼륨 분자 구조식

식별자 및 물리적 특성

CAS No.584-08-7
분자식CK2O3
평균 분자량138.205 g/mol
단동위원소 질량137.91215683 g/mol
SMILESO=C([O-])[O-].[K+].[K+]
InChIKeyBWHMMNNQKKPAPP-UHFFFAOYSA-L
PubChem CID11430
ChEMBLCHEMBL2105894
ChEBICHEBI:131526
EC No.209-529-3
DTXSIDDTXSID2036245
현지명탄산 칼륨

화학 및 물리적 성질

극성 표면적63.2
수소 결합 공여자 수0
수소 결합 수용자 수3
회전 가능 결합 수0
무거운 원자 수6
형식 전하0
복잡도18
pHpH = 11.6 (aqueous solution)10.52(1 mM solution)11(10 mM solution)11.36(100 mM solution)
냄새Odorless100.00%. 냄새 없는
맛Alkaline taste
밀도2.29 g/cu cm2.29 g/cm³2.29 @25 °C2.43 g/mL at 25 °C
Color/FormColorless cubic crystalshygroscopicGranules or granular powderWhite, deliquescent, granular, translucent powder
용해도Very soluble in water. Insoluble in ethanolFor more Solubility (Complete) data for POTASSIUM CARBONATE (6 total), please visit the HSDB record page.Insoluble in alcohol and acetone111 g/100 g water at 25 °CSoluble in 1 part cold, 0.7 part boiling water.Solubility in water (g K2CO3/100 g H2O): 105.5 at 0 °C108.0 at 10 °C110.5 at 20 °C113.7 at 30 °C155.7 at 100 °CH2O: 1 M at 20 °C, 투명, 무색
끓는 점Decomposesdecomposes [STR93]
DecompositionWhen heated to decomposition it emits toxic fumes of K2O.
녹는점899 °C891 °C891 °C (lit.)
Physical DescriptionDry PowderOther SolidLarge CrystalsCBILiquidWhite, very deliquescent powder.The hydrate occurs as small, white, translucent crystals or granulesWhite deliquescent powder[Hawley] Available as a solid (anhydrous or sesquihydrate) and concentrated solution (47% potassium carbonate)[CHEMINFO]COLOURLESS HYGROSCOPIC CRYSTALS OR HYGROSCOPIC WHITE POWDER.
Other Experimental PropertiesHygroscopicEnthalpy of fusion: 27.60 kJ/mol at 899 °CDecomposes on heating with CO2 loss.Deliquesces in moist airFor more Other Experimental Properties (Complete) data for POTASSIUM CARBONATE (6 total), please visit the HSDB record page.
저장 조건Store at +5°C to +30°C.
물리적 상태가루
pKa(산도 계수)10.33[at 20 ℃]
색상노란색
비중2.29
용해도1120g/L(20℃)
비열Cp(crystal): 0.83 J/(g·K), at 25℃
Merck14,7619
BRN4267587
유전율5.6(16.0℃)
안정성안정적인. 습기, 산, 삼불화 브롬 마그네슘 및 삼염화 브롬 마그네슘과 호환되지 않습니다.
화장품 원료 기능버퍼링
InChI1S/CH2O3.2K/c2-1(3)4/h(H2,2,3,4)/q2*+1/p-2
InChIKeyBWHMMNNQKKPAPP-UHFFFAOYSA-L
SMILES[K+].[K+].[O-]C([O-])=O
NISTDipotassium carbonate(584-08-7)
EPAPotassium carbonate (584-08-7)

화학적 성질

Potassium carbonate is a white, crystalline, salt that forms basic aqueous solutions used in the production of fertilizer, glass, ceramics, explosives, soaps, chemicals, and wool treatments. It was the main compound once referred to as potash, although the term today is not reserved exclusively for potassium carbonate, but for several potassium salts. In the fertilizer industry, potash refers to potassium oxide, K2O, rather than potassium carbonate. Pearlash is a purer form of potash made by heating potash to remove impurities.

안전 및 규제

GHS 분류This chemical does not meet GHS hazard criteria for 0.9% (25 of 2657) of reports.WarningH302 (15.4%): Harmful if swallowed [Warning Acute toxicity, oral]H315 (45%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (97.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (42.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2657 reports by companies from 73 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Reported as not meeting GHS hazard criteria per 25 of 2657 reports by companies.There are 72 notifications provided by 2632 of 2657 reports by companies with hazard statement code(s).Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
규제 정보Chemical: Carbonic acid, dipotassium saltCarbonic acid, potassium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Carbonic acid, potassium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 17-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15221Potassium carbonate: Does not have an individual approval but may be used under an appropriate group standard
기타 안전 정보IMAP assessments - Alkaline salts-carbonates: Human health tier II assessmentIMAP assessments - Carbonic acid, dipotassium salt: Environment tier I assessment
화재 위험Not combustible.
유해성 요약An irritant to tissues[Hawley] Probably a severe eye irritant[CHEMINFO] May be caustic[HSDB]
FDA 요건Substance added directly to human food affirmed as generally recognized as safe (GRAS).Potassium carbonate used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in accordance with good manufacturing or feeding practice.Drug products containing certain active ingredients offered over-the-counter (OTC) for certain uses. A number of active ingredients have been present in OTC drug products for various uses, as described below. However, based on evidence currently available, there are inadequate data to establish general recognition of the safety and effectiveness of these ingredients for the specified uses: potassium carbonate is included in antidiarrheal drug products.Drug products containing certain active ingredients offered over-the-counter (OTC) for certain uses. A number of active ingredients have been present in OTC drug products for various uses, as described below. However, based on evidence currently available, there are inadequate data to establish general recognition of the safety and effectiveness of these ingredients for the specified uses: potassium carbonate is included in digstive aid drug products.
Special ReportsEuropean Chemicals BureauESIS Database/IUCLID Dataset for Potassium Carbonate (584-08-7) (2000 CD-ROM edition) contains information on use, toxicology, and environmental effects of this chemical as supplied to the European Union by industry.[Available from, as of February 23, 2011: http://esis.jrc.ec.europa.eu/]
EPA Safer ChemicalChemical: Potassium carbonate, anhydrousGreen circle - The chemical has been verified to be of low concern based on experimental and modeled data.
FIFRA 요건Residues of carbonic acid, dipotassium salt are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops only. Use: buffering agent.As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their continued use. Under this pesticide reregistration program, EPA examines newer health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether the use of the pesticide does not pose unreasonable risk in accordance to newer saftey standards, such as those described in the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA '88 were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern than those on List C, and with List C containing pesticides of greater concern than those on List D. Potassium carbonate is found on List D. Case No: 4066Pesticide type: fungicide, herbicide, antimicrobialCase Status: None of the active ingredients in the case are being supported for reregistration by their registrants. All are unsupported, or some are unsupported and some are cancelled. Cases described as "unsupported" generally are being processed for cancellation.AI Status: The active ingredient is no longer contained in any registered pesticide products ... "cancelled."
Chemical DangersThe solution in water is a medium strong base. Reacts violently with acids and chlorine trifluoride. Reacts with powdered metals.
Hazard Classes and CategoriesAcute Tox. 4 (15.4%)Skin Irrit. 2 (45%)Eye Irrit. 2A (97.7%)STOT SE 3 (42.3%)Not ClassifiedEye damage - category 1Specific target organ toxicity (single exposure) - category 3Acute toxicity (Oral) - Category 4Skin corrosion/irritation - Category 2Serious eye damage/eye irritation - Category 2ASerious eye damage/eye irritation - Category 1Hazardous to the aquatic environment (Acute) - Category 3Hazardous to the aquatic environment (Long-term) - Category 3
Skin, Eye, and Respiratory IrritationsMay cause respiratory tract irritation...May cause skin irritation... May cause eye irritation....Irritating to skin, mucous membrane of eyes and upper respiratory tract.
Hazardous Reactivities and IncompatibilitiesIncompatible with KCOchlorine trifluoridemagnesium.The mixture of magnesium and potassium carbonate recommended by Castellana as a safe substitute for molten sodium in the Lassaigne test can itself be hazardous, as an equimolar mixture gives an explosive substance (possibly 'carbonylpotassium', potassium benzenehexoxide) on heating.Combination of chlorine trifluoride and ... potassium carbonate ... results in a violent reaction.
소화In case of fire in the surroundings, use appropriate extinguishing media.
응급 조치Fresh air, rest.Remove contaminated clothes. Rinse skin with plenty of water or shower.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .
안전 보관Dry. Separated from strong acids.
소화 절차Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not burn.Wear self contained breathing apparatus for fire fighting if necessary.
보관 조건Keep tightly closed.Potassium carbonate is stored in bunkersthe ventilation air must be dry because of the hydroscopicity of the product.Keep container tightly closed in a dry and well-ventilated place.
정리 방법Accidental release measures. Do not let product enter drains.
처리 방법SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal and plant lifeand conformance with environmental and public health regulations.Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.
누출 처리Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Wash away remainder with plenty of water.
Preventive MeasuresHand protection: handle with gloves. Eye protection: safety glasses. Skin and body protection: choose body protection according to the amount and concentration of the dangerous substance at the work place.Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.Accidental release measures. Use personal protective equipment. Avoid dust formation. Avoid breathing dust.If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact, wash off with soap and plenty of water. Consult a physician. In case of eye contact, rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed, never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.SRP: The scientific literature for the use of contact lenses by industrial workers is inconsistent. The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
Eye PreventionWear safety goggles.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.
Skin PreventionProtective gloves.
상호 작용Changes in urinary parameters (electrolyte levels and pH) and DNA synthesis and the morphology of the bladder epithelium were investigated in rats that were fed for 4 to 6 weeks on diets containing various Na, K, Mg, or Ca carbonate salts (3%) with or without L-ascorbic acid (5%). Beside increases in urinary pH and electrolyte levels, DNA synthesis in the bladder epithelium was increased in groups given sodium bicarbonate /and/ potassium carbonate with or without L-ascorbic acid. Furthermore some morphological alterations in the bladder epithelium were induced. Administration of ascorbic acid in combination with the salts induced levels of change greater than those with the salts alone. After administration of ascorbic acid with NH4Cl alone ... those effects on the bladder epithelium were not observed. Therefore, the authors suggest that the degree of DNA synthesis and/or morphological alteration in the rat bladder epithelium after treatment with various bases may depend on changes in urinary concentrations of sodium or potassium ions and/or pH and the presence of ascorbic acid in the urine.
생태독성 수치LC50Species: Ceriodaphnia dubia (Water Flea) age <24 hrConditions: freshwater, static, 25 °C, pH 7.5-9.0, dissolved oxygen >40%Concentration: 630000 ug/L for 24 hr (95% confidence interval: 580000-670000 ug/L) /technical/Concentration: 630000 ug/L for 48 hr (95% confidence interval: 580000-670000 ug/L) /technical/Species: Daphnia magna (Water Flea) age <24 hrConditions: freshwater, static, 20 °C, pH 7.5-9.0, dissolved oxygen >40%Concentration: 670000 ug/L for 24 hr (95% confidence interval: 440000-880000 ug/L) /technical/Concentration: 650000 ug/L for 48 hr (95% confidence interval: 380000-820000 ug/L) /technical/For more Ecotoxicity Values (Complete) data for POTASSIUM CARBONATE (7 total), please visit the HSDB record page.
유해 작용Dermatotoxin - Skin burns.
노출 경로The substance can be absorbed into the body by ingestion.
독성 요약The CIR Expert Panel concluded that the following 6 carbonate salts are safe in the present practices of use and concentration, as described in this safety assessment, when formulated to be non-irritating...Potassium Carbonate...Safe for use in cosmetics, with qualifications
생태독성 발췌/AQUATIC SPECIES/ Interaction of potash and Decis /Deltametarim/ in the ecophysiology of a freshwater fish, Oreochromis mossambicus, was studied. It was found that 300, 550 and 700 mg/L of potash were sublethal (LC0), median lethal (LC50), and toxic (LC100) to O. mossambicus for 96 hr exposure, respectively. Sublethal concentrations of potash and decis were exposed to fishes individually and in combination for 28 days. The results revealed that the combined effect of these chemicals was more highly toxic to food intake, growth, and conversion efficiencies than the individual chemicals.
Signs and SymptomsSore throat. Cough.Redness. Pain.Burning sensation in the throat and chest.
Human Toxicity Excerpts/OTHER TOXICITY INFORMATION/ Too strong alkali to be used internally. In large doses it is caustic irritant.
Non-Human Toxicity Excerpts/LABORATORY ANIMALS: Acute Exposure/ Rabbit skin. Irritating (Draize test) /Potassium carbonate hydrate//LABORATORY ANIMALS: Acute Exposure/ LD50 Oral (gavage) rat >2000 mg/kg (no mortalities in 15 day observation period)/LABORATORY ANIMALS: Acute Exposure/ Exptl irrigation of surface of the eyes of rabbits with 10% soln...at pH 11.6 for 30 seconds caused pain and very slight transient optical irregularity of epithelium./LABORATORY ANIMALS: Subchronic or Prechronic Exposure/ Dietary administration of 5% L-ascorbic acid plus 3% potassium carbonate to male Fischer-344 rats enhanced the development of preneoplastic and neoplastic lesions of the urinary bladder initiated with N-butyl-N-(4-hydroxybutyl)-nitrosamine. This was associated with changes in urinary parameters (elevation of pH increased potassium content, increased total ascorbic acid content). Administration of potassium carbonate without ascorbic acid increased the induction of the preneoplastic lesion, but not neoplastic lesions.For more Non-Human Toxicity Excerpts (Complete) data for POTASSIUM CARBONATE (10 total), please visit the HSDB record page.
Probable Routes of Human ExposureAccording to the 2006 TSCA Inventory Update Reporting data, the number of persons reasonably likely to be exposed in the industrial manufacturing, processing, and use of potassium carbonate is 1000 or greaterthe data may be greatly underestimated(1).NIOSH (NOES Survey 1981-1983) has statistically estimated that 478,866 workers (139,011 of these were female) were potentially exposed to potassium carbonate in the US(1).
Antidote and Emergency Treatment/SRP:/ Immediate first aid: Remove patient from contact with the material. Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Inorganic Bases/Alkaline Corrosives and Related Compounds//SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 6 to 12 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool ... . Do not attempt to neutralize. Cover skin burns with dry sterile dressings after decontamination ... . /Inorganic Bases/Alkaline Corrosives and Related Compounds//SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Early intubation, at the first signs of upper airway obstruction, may be necessary. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Inorganic Bases/Alkaline Corrosives and Related Compounds/
Toxicity DataLC (rat) = > 500 mg/m3
수질 위해 등급(WGK)1
TSCA 등재 상태TSCA listed
RTECS 번호TS7750000
운송 번호(UN)3262
독성LD50 orally in rats: 1.87 g/kg, H. F. Smyth et al., Am. Ind. Hyg. Assoc. J. 30, 470 (1969)
관세 코드28364000
위험 문구(R)22-36/37/38-20/21/22
위험 표시Xn
안전 문구(S)26-36-37/39
포장분류III
위험 등급8Eye Irrit. 2Skin Irrit. 2STOT SE 3
기존화학 물질KE-29083
F 고인화성물질3
저장 분류13 - Non Combustible Solids
유해 물질 데이터584-08-7(Hazardous Substances Data)

용도

용도

무기 산업은 타르타르산 나트륨 칼륨, 불화 칼륨 알루미늄, 티오시 안산 칼륨 및 이산화 티탄을 생산하는 데 사용됩니다. 제약 산업은 오래 지속되는 술폰 아미드, 프로게스테론, 코르티 존, 클로르헥시딘 및 에스트라 디올 벤조 에이트를 제조하는 데 사용됩니다. 유리 제품 산업은 탄탈륨 분말을 준비하여 레벨링 특성을 향상시키고 유리에 플럭스를 추가하며 유리의 투명성과 굴절률을 증가시키는 데 사용됩니다. 염료 산업은 인디 틴 숲 (Indanthine forest)을 제조하고, 적색 3B를 분산시키고, 회분 M을 감소시키는 등의 용도로 사용됩니다. 인쇄 및 염색 산업은 부가 가치세 염료의 인쇄 및 염색 및 얼음 염료의 미백에 사용됩니다. 고무 산업은 4010 개의 노화 방지제를 만드는 데 사용됩니다. 모직 면화 산업은 면화 정련 및 양모 탈지에 사용됩니다. 탄산 칼륨은 중요한 무기 화학 물질, 의약품 및 경공업 자재 중 하나입니다. 그것은 주로 광학 유리, 용접 전극, 전자 튜브, 텔레비전 사진 튜브, 전구, 인쇄 및 염색, 염료, 잉크, 사진 약물, 나트륨 규산염, 폴리 에스테르, 폭발물에 사용됩니다. , 전기 도금, 선탠, 도자기, 건축 자재, 크리스탈, 칼륨 비누 및 의약품 생산. 가스 흡착제, 건조 분말 소화 약제, 고무 노화 방지제로 사용됩니다. 화학 비료 합성 가스에서 이산화탄소를 제거하는데도 사용됩니다. 칼륨 함유 비료로 사용할 수도 있습니다. 첨단 기술의 지속적인 발전으로 세제 첨가제, MSG, 식품 및 기타 분야에서의 탄산 칼륨의 응용 또한 확대되고 있습니다. 탄산 칼륨은 주로 칼륨 유리, 칼륨 비누 및 기타 무기 화학 물질의 제조뿐만 아니라 산업 가스에서 황화 수소 및 이산화탄소의 제거뿐만 아니라 용접 전극, 잉크 제조, 인쇄 및 염색 산업.

용도

Potassium carbonate is used in the chemical industry as a source of inorganic potassium salts (potassium silicates, potassium bicarbonate), which are used in fertilizers, soaps, adhesives, dehydrating agents, dyes, and pharmaceuticals. Potassium carbonate used to make potassium lye produces soft soaps, which are liquids or semisolids rather than solids. Other uses of potassium carbonate includes use as a fire suppressant in extinguishers, as a CO2 absorbent for chemical processes and pollution control, an antioxidant in rubber additives, and in pharmaceutical formulations.

일반 설명

Potassium carbonate (K2CO3) is a white salt, soluble in water (insoluble in ethanol) which forms a strongly alkaline solution. It can be made as the product of potassium hydroxide's absorbent reaction with carbon dioxide. It presents a large capacity to absorb moisture.Corrosive to metals and tissue. Density 12.8 lb /gal. Used to make soaps, other potassium compounds, in liquid fertilizers.

제조 및 합성 방법

생산 방법

Potassium carbonate can be obtained from ash or by electrolysis of potassium chloride. Another method involves reacting potassium hydroxide with carbon dioxide. The resulting liquid carbonate contains approximately 50% potassium carbonate in water. However, the solid product, which contains over 70% potassium carbonate, is expensive and only suitable for certain types of acidic soil. Additionally, neutralizing caustic potash with carbon dioxide also yields potassium carbonate.