(2-Dicyclohexylphosphino-2,6-diisopropoxy-1,1-biphenyl)(2-(2-amino-1,1-biphenyl))palladium(II) methanesulfonate

HCID 117064724CAS 1445085-77-7
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
CC(C)Oc1cccc(OC(C)C)c1-c1ccccc1P(C1CCCCC1)C1CCCCC1.CS(=O)(=O)O.Nc1ccccc1-c1[c-]cccc1.[Pd]
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
분자식
C43H57NO5PPdS-
평균 분자량
837.4 g/mol

이름 및 식별자

우선 이름
(2-Dicyclohexylphosphino-2,6-diisopropoxy-1,1-biphenyl)(2-(2-amino-1,1-biphenyl))palladium(II) methanesulfonate
IUPAC
dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylaniline
영어명
RuPhos Pd G3
분자식
C43H57NO5PPdS-
분자량
837.375141

이름 및 동의어

1445085-77-7(2-Dicyclohexylphosphino-2,6-diisopropoxy-1,1-biphenyl)(2-(2-amino-1,1-biphenyl))palladium(II) methanesulfonate(2-Dicyclohexylphosphino-2,6-diisopropoxy-1,1-biphenyl)[2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonateRefChem:395738809-028-5RuPhos-Pd-G3dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylanilineMethanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)Pd(II)2-pheRuPhos Pd G3, 95%Palladium, [2'-(amino-kappaN)[1,1'-biphenyl]-2-yl-kappaC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-kappaP](methanesulfonato-kappaO)-SCHEMBL23043022
이름 더 보기
methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii)Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)RuPhos Palladacycle Gen.3RuPhos-G3-PalladacycleRuPhos Pd G3RuPhos Pd G3 95%RuPhos Pd G3 ChemBeadsRuPhos Pd G3 ISO 9001：2015 REACHMethanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...
F10291EN300-7401839doi:10.14272/AXZLIMCJMPNFFU-UHFFFAOYSA-M.1(2-Dicyclohexylphosphino-2 inverted exclamation marka,6 inverted exclamation marka-diisopropoxy-1,1 inverted exclamation marka-biphenyl)[2-(2 inverted exclamation marka-amino-1,1 inverted exclamation marka-biphenyl)]palladium(II) methanesulfonate[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-2-yl]dicyclohexylphosphane; {2'-amino-[1,1'-biphenyl]-2-yl}palladio methanesulfonate

데이터베이스 식별자

CAS
1445085-77-7
PubChem CID
117064724
EC Number
809-028-5

물성

구조 계산 물성

극성 표면적
107 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
7
회전 가능 결합 수
9
무거운 원자 수
52

물리화학적 성질

녹는점
188 · 188-196°C (decomposition)
저장 조건
2 · under inert gas (nitrogen or Argon) at 2–8 °C
물리적 상태
가루
색상
하얀색
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
SMILES
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 데이터

wgk
3
risk_code
36/37/38-52/53
hazard_code
Xi
safety_code
26-61
Hazard Classifications
Aquatic Chronic 3Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스
11 - Combustible Solids

화학 및 산업

응용 분야 · 2건

용도RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.Suzuki-Miyaura-cross-coupling of aminothiophenes.

일반 설명RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

상·하류 제품 정보

공급사50 곳

新乡市润宇新材料科技有限公司15690792173 · [email protected]
武汉敬康恩生物医药科技有限公司13720134139 086-15871494362 13720134139 · [email protected]
上海毕合生物化学技术有限公司13816464724 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]

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