Tert-Butyllithium

HCID 53628101CAS 594-19-4

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: C[C](C)C.[Li]
InChIKey: BKDLGMUIXWPYGD-UHFFFAOYSA-N
분자식: C4H9Li
평균 분자량: 64.1 g/mol
단동위원소 질량: 64.08642984

이름 및 식별자

우선 이름: Tert-Butyllithium
IUPAC: tert-Butyllithium

이름 및 동의어

RefChem:896574DTXCID701022987209-831-5594-19-4DTXSID60883457Lithium, (1,1-dimethylethyl)-Tert-Butyllithium

데이터베이스 식별자

CAS: 594-19-4
PubChem CID: 53628101
DTXSID: DTXSID60883457
EC Number: 209-831-5

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 0
무거운 원자 수: 5
형식 전하: 0
복잡도: 4.8

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Organic Compounds

Physical Description15% n-pentane solution: Yellow liquid; [Alfa Aesar MSDS]

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P223, P231, P231+P232, P233, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 72 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 3건

Chemical: Lithium, (1,1-dimethylethyl)-

REACH registered substance: tert-butyllithium (EC: 209-831-5)

Lithium, (1,1-dimethylethyl)-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Lithium, (1,1-dimethylethyl)-: Environment tier I assessment

Hazards Summary15% n-pentane solution: Pyrophoric; Reacts violently with water evolving extremely flammable gases; Causes burns; Harmful by ingestion (may cause lung damage by aspiration); [Alfa Aesar MSDS] See Lithium. See Phenyllithium.

Hazard Classes and CategoriesPyr. Sol. 1 (100%)

CSL Reaction Information · 6건

CSL00136

TERT-BUTYLLITHIUM + N,N,N',N'-TETRAMETHYLDIAMINOMETHANE

Potential Explosion Hazard Of -Lithiated Amines

Explosive

M (up to 100g)

5.6 g of isolated lithiated bis(dimethylamino)-methane cause explosion when drying in vacuo

안전 및 보호

Protective Action Criteria (PAC) · 3건

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

화학 및 산업

용도 및 제조

General Manufacturing InformationLithium, (1,1-dimethylethyl)-: ACTIVE

연결된 노트

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