마그네슘 포스피드

Magnesium phosphide

HCID 61546CAS 12057-74-8

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기본 정보

표준 SMILES
[Mg+2].[Mg+2].[Mg+2].[P-3].[P-3]
InChIKey
VUBDMGXNLNDGIY-UHFFFAOYSA-N
분자식
Mg3P2
평균 분자량
134.863 g/mol
단동위원소 질량
133.90264836

이름 및 식별자

우선 이름
Magnesium phosphide
현지명
마그네슘 포스피드
영어명
Magnesium phosphide
분자식
Mg3P2
분자량
134.86

이름 및 동의어

인화마그네슘마그네슘포스피드마그네슘포스피드MagtoxinFumi-CelEinecs 235-023-7Caswell no. 532bMagnesiumphosphidFosfuri di magnesioMAGNESIUM PHOSPHIDEtrimagnesium diphosphideMagnesium phosphide (Mg3P2)
이름 더 보기
Fosfuri di magnesio [italian]

데이터베이스 식별자

CAS
12057-74-8
PubChem CID
61546
DTXSID
DTXSID0034691
UNII
Q846538H9E
EC Number
235-023-7

물성

물리화학적 성질

녹는점
750 °C · 750 °C
밀도
2.06 · 2.060
용해도
2 O · reacts with H2O
물리적 상태
노란색 입방 결정
색상
yellow cubic crystals, crystalline
수용성
2 O에 · H2O에 의해 분해됨 [KIR82]

화학적 성질

shiny grayish yellow; stable in dry air; decomposed by moisture; can be prepared directly from magnesium and phosphorus; used with igniting agent such as 1% HNO3 in sea flares [KIR82]

안전 및 규제

안전 데이터

tsca
TSCA listed
ridadr
UN 2011
risk_code
15/29-28-50
hazard_code
F,T+,N
safety_code
22-43-45-61
포장분류
I

화학 및 산업

응용 분야 · 3건

개요Magnesium phosphide has the formula of Mg3P2 and themolecularweight of 134.9456 g/mol.It is a yellow cubic crystal having a density of 2.06 g/cm. It reacts violently with water and may ignite upon contact with air. It is toxic by ingestion. It has a slight odor of garlic. It is not combustible but forms a flammable gas on contact with water or damp air: Mg3P2 (solid) + 6H2O (liq)3Mg(OH)2 (solid) + 2PH3 (gas) Mg3P2 burns in air or oxygen at a dull red heat to form a phosphate, and reacts with chlorine gas to form: Mg3P2 (solid) + Cl2MgCl2 + PCl3

용도Magnesium phosphide has found several uses in industry. It reacts with moisture in the atmosphere to produce phosphine gas which is the substance that is active as a pesticide to control insects and rodents. It is primarily used for indoor fumigation of raw agricultural commodities, animal feeds, processed food commodities, and nonfood commodities in sealed containers or structures, and for outdoor fumigation of burrows to control rodents and moles in nondomestic areas, noncropland, and agricultural areas. Aluminum and magnesium phosphide are formulated as tablets, pellets, impregnated materials and dusts. Aluminum and magnesium phosphide are restricted use chemicals. With magnesium phosphide, a fumigant is available which can be used for fumigating tobacco even at low temperatures.Magnesium phosphide treatment of dried-fig stacks at 600 and 1000 ppm phosphine for 3 days under tarpaulin were compared with the standard method of control, Methyl bromide. The tested concentrations and exposure periods for Mg3P2 provided 100% mortality in test insects and no negative effect on fruit quality for 9 months in storage under ambient conditions. In contrast, fruit quality with CH3Br did not match that of PH3-treated fruit. Magnesium phosphide has also been used to control insects in stored almonds, barley, brazil nuts, cashews, cocoa beans, coffee beans, corn, cottonseed, dates, filberts, flower seed, grass seed,millet,oats, peanuts, pecans, pistachio nuts, popcorn, rice, rye, sorghum, soybeans, sunflower seed, triticale, walnuts, wheat, vegetable seed, animal feed or feed ingredients.

일반 설명Magnesium phosphide is a white crystalline solid. Magnesium phosphide reacts violently with water and may ignite upon contact with air. Magnesium phosphide is toxic by ingestion. Magnesium phosphide is used to make other chemicals.

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