트리옥틸 인산염

Tris(2-ethylhexyl) phosphate

HCID 6537CAS 78-42-2

기본 정보

표준 SMILES
CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC
InChIKey
GTVWRXDRKAHEAD-UHFFFAOYSA-N
분자식
C24H51O4P
평균 분자량
434.6 g/mol
단동위원소 질량
434.35249674

개요

Tris(2-ethylhexyl)phosphate is a clear colorless to pale yellow liquid with a slight sharp odor. (NTP, 1992)

이름 및 식별자

우선 이름
Tris(2-ethylhexyl) phosphate
IUPAC
tris(2-ethylhexyl) phosphate
현지명
트리옥틸 인산염
영어명
Tris(2-ethylhexyl) phosphate
분자식
C24H51O4P
분자량
434.63

이름 및 동의어

Tris(2-ethylhexyl) phosphate78-42-2Tris(2-ethylhexyl)phosphateTri(2-ethylhexyl) phosphatePhosphoric acid, tris(2-ethylhexyl) ester2-Ethyl-1-hexanol phosphateTEHPDTXSID0021414BQC0BKB72SNSC-407921DTXCID801414RefChem:191857
이름 더 보기
인산트리스(2-에틸헥실)에스터트리스(2-에틸헥실)인산염트리옥틸인산염인산트리스(2-에틸헥실)에스터TOPTRIOCTYL PHOSPHATETRI(2-AmgardTOFflexoltofFlexol TOFNCI-C54751kronitextof
201-116-6Tris(2-ethylhexy)phosphateNSC 407921Tri(ethylhexyl) phosphateTris-(2-ethylhexyl)fosfatMFCD00009491Tris-2(2-ethylhexyl)fosfat [Czech]1-Hexanol, phosphate

데이터베이스 식별자

CAS
78-42-2
PubChem CID
6537
DTXSID
DTXSID0021414
ChEMBL
CHEMBL1562290
ChEBI
CHEBI:181994
UNII
BQC0BKB72S
EC Number
201-116-6
Nikkaji
J1.953D

물성

구조 계산 물성

XLogP
8.9
극성 표면적
44.8 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
21
무거운 원자 수
29

실험 및 물리화학적 성질

Chemical ClassesOrganophosphate
LogP4.23
Density · 3건

0.9262 at 68 °F (NTP, 1992) - Less dense than water; will float

Relative density (water = 1): 0.93

0.9077 @25 °C

Flame RetardantsFlame Retardants -> Organophosphorus flame retardant (OP)
Solubility · 2건

less than 1 mg/mL at 64 °F (NTP, 1992)

Solubility in water at 20 °C: none

Flash Point · 2건

305 °F (NTP, 1992)

170 °C

물리화학적 성질

녹는점
-70 °C · -70°C
끓는 점
215 °C4 · 215 °C4 mm Hg(lit.)
밀도
0.92 g/mL · 0.92 g/mL at 20 °C(lit.)
증기압
2.1 mm · 2.1 mm Hg ( 20 °C)
굴절률
20 · n20/D 1.444(lit.)
인화점
230 °F · >230 °F
화학적 성질 · 1건

Tris(2-ethylhexyl) phosphate, a clear, viscous liquid, is used as a component of vinyl stabilizers, grease additives, and flame-proofing compositions; however, it is used primarily as a plasticizer for vinyl plastic and synthetic rubber compounds. Tris(2-ethylhexyl) phosphate has been employed as a specialty flameretardant plasticizer for vinyl compositions where low temperature flexibility is critical, eg, in military tarpaulins. It can be included in blends with general purpose plasticizers such as phthalate esters to improve low temperature flexibility.

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 52.7% (260 of 493) of all reports.

Warning

H315 (42%): Causes skin irritation [Warning Skin corrosion/irritation]

P264, P264+P265, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, and P362+P364 (click each P-code to see the statement)

Aggregated GHS information provided per 493 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

유해성 정보

Regulatory Information · 4건

Chemical: Phosphoric acid, tris(2-ethylhexyl) ester

Phosphoric acid, tris(2-ethylhexyl) ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphoric acid, tris(2-ethylhexyl) ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Tris(2-ethylhexyl) phosphate (EC: 201-116-6)

Tris (2-ethylhexyl) phosphate: Does not have an individual approval but may be used under an appropriate group standard

Fire Hazards · 2건

This chemical is combustible. (NTP, 1992)

Combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health Hazards · 1건

SYMPTOMS: Symptoms of exposure to this compound include irritation of the skin and eyes. Skin contact may cause discomfort, itching, reddening and swelling of the skin. Eye contact may cause discomfort, redness, tearing and swelling. Other symptoms may include difficult breathing and pulmonary edema.

Reactive GroupEsters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
Reactivity ProfileTRIS(2-ETHYLHEXYL)PHOSPHATE is incompatible with oxidizing materials. It may soften or deteriorate certain plastics and elastomers. It is incompatible with cellulose acetate and cellulose acetate butyrate. (NTP, 1992)
Chemical DangersDecomposes on heating. This produces toxic fumes of phosphine and phosphorus oxides. Reacts with oxidants.

안전 및 보호

Fire Fighting · 2건

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

Use water spray, powder, foam, carbon dioxide.

First Aid Measures · 4건

Fresh air, rest. Refer for medical attention.

Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two glasses of water to drink. Refer for medical attention .

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Safe StorageSeparated from strong oxidants. Well closed. Keep in a well-ventilated room.
Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Spillage DisposalCollect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

독성 정보

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
Signs and Symptoms · 2건

Redness. Pain.

Redness. Pain.

ICSC Environmental DataAvoid release to the environment in circumstances different to normal use.
Carcinogen Classification · 6건

Tris(2-ethylhexyl) phosphate

TR-274: Toxicology and Carcinogenesis Studies of Tris(2-ethylhexyl)phosphate (CASRN 78-42-2) in F344/N Rats and B6C3F1 Mice (Gavage Studies) (1984 )

10/28/83

Equivocal Evidence

No Evidence

No Evidence

RAIS Toxicity Values · 4건

0.1

PPRTV Current

0.0032

PPRTV Current

EPA Provisional Peer-Reviewed Toxicity Values · 5건

Tris(2-ethylhexyl)phosphate

1 x 10^-1 mg/kg-day

PDF Document

Suggestive evidence of carcinogenic potential

2002

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
MP0770000
독성
LD50 orally in Rabbit: 37000 mg/kg LD50 dermal Rabbit 20000 mg/kg
HS 번호
29190090
risk_code
38

화학 및 산업

용도 및 제조

U.S. Production2023: 5,000,000 - <10,000,000 lb
Consumer UsesFlame retardant
Industry UsesProcessing aids, not otherwise listed
General Manufacturing Information · 2건

Petroleum Lubricating Oil and Grease Manufacturing

Phosphoric acid, tris(2-ethylhexyl) ester: ACTIVE

응용 분야

용도Solvent, antifoaming agent, plasticizer.

일반 설명Clear colorless to pale yellow liquid with a slight sharp odor. Insoluble in water; Soluble in alcohol, acetone, and ether. Combustible.

상·하류 제품 정보

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]

관련 반응

0건

현재 필터 조건에 해당하는 반응 기록이 없습니다.

연결된 노트

불러오는 중…