Magnesium, bromoethenyl-

HCID 74584CAS 1826-67-1
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
[Br-].[CH-]=C.[Mg+2]
InChIKey
XHHHAXOHMKAOSL-UHFFFAOYSA-M
분자식
C2.H3.Br.Mg
평균 분자량
131.25 g/mol

이름 및 식별자

우선 이름
Magnesium, bromoethenyl-
IUPAC
magnesium;ethene;bromide
영어명
Vinylmagnesium bromide
분자식
C2H3BrMg
분자량
131.26

이름 및 동의어

Vinylmagnesium bromide1826-67-1Magnesium, bromoethenyl-BromovinylmagnesiumDTXSID40883758EINECS 217-375-3Magnesium, bromoethenylRefChem:800647DTXCID901023250217-375-3magnesium;ethene;bromidebromo(ethenyl)magnesium
이름 더 보기
bromoethenyl-magnesiuVinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)PEFC-0280.98g/ml，20℃bromoethenyl-magnBromvinylmagnesiumBromoethenylmagnesiumVinyl Bromo magnesiumVINYLMAGNESIUMBROMICLC
vinyl magnesium bromideBromidoethenylmagnesiumVinyl magnesium bromide solutionMFCD00000042Vinylmagnesium bromide, 0.7 M in THF, packaged in resealable ChemSeal bottlesVinylmagnesiumbromidebromo(vinyl)magnesiumvinyl magnesiumbromide

데이터베이스 식별자

CAS
1826-67-1
PubChem CID
74584
DTXSID
DTXSID40883758
EC Number
217-375-3

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
4

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Organic Compounds
Density0.98 @25 °C
Physical Description12-17% tetrahydrofuran solution: Brown liquid with an ether-like odor; [Alfa Aesar MSDS]

물리화학적 성질

밀도
0.981 g/mL · 0.981 g/mL at 25 °C
인화점
1 °F · 1 °F
저장 조건
Refrigerator
용해도
격렬한 반응
물리적 상태
액체
색상
투명하고 밝은 갈색에서 갈색까지

화학적 성질

Clear light brown to brown solution

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (39.7%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 68 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationMagnesium, bromoethenyl-: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary12-17% in tetrahydrofuran (CAS# 109-99-9): Pyrophoric; Reacts violently with water evolving extremely flammable gases; May form explosive peroxides; Causes burns; [Alfa Aesar MSDS] See Vinylmagnesium chloride.
Hazard Classes and CategoriesFlam. Liq. 2 (39.7%)

안전 및 보호

Protective Action Criteria (PAC) · 3건

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk
1
tsca
TSCA listed
ridadr
UN 3399 4.3/PG 2
HS 번호
29319090
risk_code
11-14-19-34-14/15-40-37
hazard_code
F,C

화학 및 산업

용도 및 제조

General Manufacturing InformationMagnesium, bromoethenyl-: ACTIVE
응용 분야 · 1건

용도Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.It may also be used in the following transformations: (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.(R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.(4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.Ethyl levulinate to -methyl--vinylbutyrolactone.

상·하류 제품 정보

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海策嵘生物科技有限公司[email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]
爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

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