Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Amino-1-(2-mercapto-2-methylpropylamino)benzene → 1-[2-(trans-2-Butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Amino-1-(2-mercapto-2-methylpropylamino)benzene | HCID 10012927 | — |
| 반응물 | 2-(trans-2-Butenylthio)-2-methylpropanal | HCID 10351953 | — |
| 생성물 | 1-[2-(trans-2-Butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene | HCID 10020049 | 88.3% |
반응 단계
2-Amino-1-(2-mercapto-2-methylpropylamino)benzene (0.36 g, 1.84×10-3 mol) and 0.58 g (3.67×10-3 mol, 200 M%) 2-(trans-2-butenylthio)-2-methylpropanal were reacted by the procedures in Example 2 to give 0.55 g (88% yield) 1-[2-(trans-2-Butenylthio)-2-methylpropylamino]-2-(2-mercapto-2-methylpropylamino)benzene as an oil after purification by radial chromatography on a 4 mm silica plate eluting with 100% hexane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05080884 |
| 출처 데이터셋 | uspto-grants-1992_01 |
| ORD ID | ord-4210ea059eb54fd6b98944dc8324a930 |
| 출처 메모 | uspto-grants-1992_01 |