Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dichloromethane → 12-Chloro-6-chrysenecarbaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | Chrysene, 6-chloro- | HCID 56969 | — |
| 반응물 | 6-Chrysenecarbaldehyde | HCID 12438774 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | 12-Chloro-6-chrysenecarbaldehyde | HCID 13375389 | — |
반응 단계
6-Chlorochrysene (Cambridge Chemical, Inc., 70 g, 0.266 mol) was formylated according to the procedure outlined in 1A, except that CH2Cl2 (2.5 L) was used as the reaction solvent. Chromatography on a plug of SiO2 (1 kg) using EtOAc as the eluting solvent afforded after removal of solvent and drying 19.1 g (25%) of 12-chloro-6-chrysenecarbaldehyde mp 255°-257°, (EtOAc).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04810727 |
| 출처 데이터셋 | uspto-grants-1989_03 |
| ORD ID | ord-8730c7835eaa4001a52c5eb3fe9fd6f2 |
| 출처 메모 | uspto-grants-1989_03 |