Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Chloride → N~9~,N~10~-Bis(trimethylsilyl)phenanthrene-9,10-diimine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Chloride | HCID 312 | — |
| 반응물 | 9,10-Phenanthrenedione | HCID 6763 | — |
| 반응물 | Sodium bis(trimethylsilyl)amide | HCID 2724254 | — |
| 반응물 | 1,2-Phenanthrenedione | HCID 3080566 | — |
| 반응물 | Phenanthrenequinone diimine | HCID 86745785 | — |
| 생성물 | N~9~,N~10~-Bis(trimethylsilyl)phenanthrene-9,10-diimine | HCID 71349758 | 37% |
반응 단계
Ligand Synthesis. 9,10-Phenanthrenequinone bis((trimethylsilyl)-imine) (silylphi) was synthesized from 9,10-phenanthrenequinone (Aldrich) and sodium bis(trimethylsilyl)amide (Fluka) as described by Tuchtenhagan and Ruhlmann. (11) Important modifications to this synthesis include a reaction temperature of no greater than 65° C. and a final phenanthrenequinone concentration of 0.08 M. Under these conditions, orange crystalline silylphi was obtained in 37% yield and stored under nitrogen. The phenanthrenequinone diimine ligand (phi) was generated and chelated in situ by combining the silylated imine ligand with an ethanolic solution of metal chloride by using a modificaiton of Schlosser's method. (12)
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05112974 |
| 출처 데이터셋 | uspto-grants-1992_05 |
| ORD ID | ord-0f445a9289244094b55915f4cb38ef55 |
| 출처 메모 | uspto-grants-1992_05 |