Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
10-Undecenal → 11-(Triethoxysilyl)undecanal
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 10-Undecenal | HCID 8187 | — |
| 반응물 | Triethoxysilane | HCID 13830 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 11-(Triethoxysilyl)undecanal | HCID 11515490 | 30% |
반응 단계
To a solution of 16.8 g 10-undecenal in 25 ml methylene chloride, crystals of di-μ-chlorodichlorobis(ethylene)-diplatinum (II) were added and the solution heated to 40°-45° C. A solution of 16.4 g triethoxysilane in 25 ml methylene chloride was added dropwise over a period of 90 minutes. After reagent addition was completed, the rection mixture was heated for an additional 30 minutes. The mixture was fractionated and the product, 11-triethoxysilylundecanal (I) was obtained at 65° C. at 0.2 mm Hg at a 30% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05277813 |
| 출처 데이터셋 | uspto-grants-1994_01 |
| ORD ID | ord-57e1e8353f3d47c19d3fc0d1c0d98e28 |
| 출처 메모 | uspto-grants-1994_01 |