Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-(Bromomethyl)-3-phenoxybenzene → m-Phenoxybenzyl 2-isopropyl-4-(o-chlorophenyl)-3-butenoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-(Bromomethyl)-3-phenoxybenzene | HCID 94544 | — |
| 반응물 | 2-(2-Chlorophenyl)acetaldehyde | HCID 11378624 | — |
| 반응물 | HCID 53812558 | HCID 53812558 | — |
| 반응물 | 2-Isopropyl-4-(o-chlorophenyl)-3-butenoic acid | HCID 54528296 | — |
| 반응물 | KOH MeOH Water | HCID 86591755 | — |
| 생성물 | m-Phenoxybenzyl 2-isopropyl-4-(o-chlorophenyl)-3-butenoate | HCID 54240396 | — |
반응 단계
The process of Example 3 is repeated using o-chlorophenylacetaldehyde to prepare ethyl 2-isopropyl-4-(o-chlorophenyl)-3-butenoate, which is hydrolyzed (potassium hydroxide-water/methanol) to the acid, 2-isopropyl-4-(o-chlorophenyl)-3-butenoic acid. The acid is reacted with m-phenoxybenzyl bromide as in Example 1 to yield m-phenoxybenzyl 2-isopropyl-4-(o-chlorophenyl)-3-butenoate. MS m/e 420 (M+).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04204071 |
| 출처 데이터셋 | uspto-grants-1980_05 |
| ORD ID | ord-cea0b473752c47b5ad7e966fcd44a7ba |
| 출처 메모 | uspto-grants-1980_05 |