Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
6-(4'-Decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid benzyl ester → 6-(4'-Decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 6-(4'-Decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid benzyl ester | HCID 54439972 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 6-(4'-Decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid | HCID 19070025 | 93% |
반응 단계
Hydrogen gas was blown into a mixture of 0.53 g (1.0 mmol) of 6-(4'-decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid benzyl ester, 0.11 g of 5% palladium/carbon and 10 ml of tetrahydrofuran with stirring at room temperature and ordinary pressure for 15 hours. The reaction mixture was filtered using Celite as a filter aid, and the filtrate was concentrated to obtain 0.42 g (0.93 mmol) of 6-(4'-decyloxybenzoyloxy)-5,6,7,8-tetrahydronaphthalene-2-carboxylic acid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05725798 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-ccd7d3bc80234865b14e3c2556c0baf6 |
| 출처 메모 | uspto-grants-1998_03 |