Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Dithionite → 2,2'-Bithiophene-5-carboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Dithionite | HCID 24489 | — |
| 반응물 | 5-Acetyl-2,2'-bithienyl | HCID 606422 | — |
| 반응물 | Sodium Hypochlorite | HCID 23665760 | — |
| 생성물 | 2,2'-Bithiophene-5-carboxylic acid | HCID 150965 | — |
반응 단계
35 ml of NaOCl solution was heated to 55° C. and 5-acetyl-2,2'-bithiophene was then added and stirred at 60°-70° C. for 2 hours. Then the reaction solution was cooled by ice bath and aqueous Na2S2O4 solution was added for removing the residual NaOCl. The reaction mixture was acidified by HCl(aq) and filtered to obtain golden product. The product was further recrystallized with 95% ethanol. The melting point of the product was 183-184%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05602170 |
| 출처 데이터셋 | uspto-grants-1997_02 |
| ORD ID | ord-560a5760db2f4c50a9267b1500ae651c |
| 출처 메모 | uspto-grants-1997_02 |