Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → Methyl (2-formyl-5-methylphenoxy)acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | Methyl bromoacetate | HCID 60984 | — |
| 반응물 | 2-Hydroxy-4-methylbenzaldehyde | HCID 61200 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | Methyl (2-formyl-5-methylphenoxy)acetate | HCID 54288233 | 91.8% |
반응 단계
By the method of Example 1, Step F, 8,27 g (0.060 mole) of 4-methylsalicylaldehyde and 11.15 g (0.073 mole) of methyl bromoacetate were reacted in the presence of 10.1 g (0.073 mole) of anhydrous potassium carbonate in 150 mL of acetone, yielding 11.47 g of methyl (2-formyl-5-methylphenoxy)acetate as a white solid, m.p. 63°-64° C. The NMR was consistent with the proposed structure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05674810 |
| 출처 데이터셋 | uspto-grants-1997_10 |
| ORD ID | ord-c120b0d135c34dbe97c7fcaea1016350 |
| 출처 메모 | uspto-grants-1997_10 |