Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Peracetic Acid → 1,5-Methano-3H-cyclopent[c]oxepin-3-one, octahydro-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Peracetic Acid | HCID 6585 | — |
| 반응물 | 4,7-Methano-5H-inden-5-one, octahydro- | HCID 96509 | — |
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 1,5-Methano-3H-cyclopent[c]oxepin-3-one, octahydro- | HCID 108360 | — |
반응 단계
18 g of a 50 % peracetic acid solution in acetic acid containing 1 g of sodium acetate were added to a stirred mixture of 15 g of tricyclo[5.2.1.02,6 ]decane-8-one (which can be purchased from Ruhrchemie, Bruchstrasse, D-42 Oberhausen Holten, West Germany) and 9 g of anhydrous sodium acetate in 60 g of dichloromethane. The temperature of the reaction mixture was kept at 20°-25° by external cooling by means of a ice-water bath during the whole addition, then it was kept at this value during 48 hours while stirring.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03981892 |
| 출처 데이터셋 | uspto-grants-1976_09 |
| ORD ID | ord-2a81ae180fb44228ac443efbfe7440b9 |
| 출처 메모 | uspto-grants-1976_09 |