Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1661854생성일: 2026년 10월 24일
Trimethylolpropane diallyl ether → [3-(2-Hydroxymethyl-2-{3-[hydroxy-(2,4,4-trimethylpentyl)-phosphinoyl]-propoxymethyl}-butoxy)-propyl]-(2,4,4-trimethylpentyl)-phosphinic acid
https://huagongshe.com/ko/reaction/1661854
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Trimethylolpropane diallyl ether | HCID 61196 | — |
| 반응물 | HCID 178460681 | HCID 178460681 | — |
| 촉매 | Di-tert-amyl peroxide | HCID 25320 | — |
| 생성물 | [3-(2-Hydroxymethyl-2-{3-[hydroxy-(2,4,4-trimethylpentyl)-phosphinoyl]-propoxymethyl}-butoxy)-propyl]-(2,4,4-trimethylpentyl)-phosphinic acid | HCID 57909086 | 100.1% |
반응 단계
10 g (0.056 moles) of 2,4,4-trimethylpentyl phosphinic acid, 6.01 g (0.028 moles) of trimethylolpropane diallyl ether and 0.4 mL (0.0019 moles) of di-tert-amylperoxide are mixed in a 100 mL single neck flask. The mixture is purged with argon to remove oxygen and is heated under argon for 6 hours at 140° C. Tert-amyl alcohol is removed by distillation and 16 g (quantitative yield) of [3-(2-hydroxymethyl-2-{3-[hydroxy-(2,4,4-trimethylpentyl)-phosphinoyl]-propoxymethyl}-butoxy)-propyl]-(2,4,4-trimethylpentyl)-phosphinic acid is obtained as a viscous oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US08030435B2 |
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| 출처 데이터셋 | uspto-grants-2011_10 |
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| ORD ID | ord-32b83ec0f54242348999164dcb2f3216 |
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| 출처 메모 | uspto-grants-2011_10 |
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