Boric Acid → Boric acid, calcium salt

HRID 1768889

반응식

HRID 1768889 반응식
C(=O)([O-])[O-].[Ca+2:5].[Ca].[OH-].[Ca+2].[OH-].[B:10]([OH:13])([OH:12])[OH:11]>CCCCCC.C1(C)C(C)=CC=CC=1>[B:10]([O-:13])([O-:12])[O-:11].[Ca+2:5].[B:10]([O-:13])([O-:12])[O-:11].[Ca+2:5].[Ca+2:5]

참가 물질

7

반응물 4

HCID 7628Boric AcidHCID 10112Calcium CarbonateHCID 5460341Calcium2회HCID 6093208Calcium Hydroxide

생성물 1

HCID 134660Boric acid, calcium salt

시약·촉매·용매 2

HCID 7237O-Xylene용매HCID 8058Hexane용매

반응 조건

온도
60 °C

실험 절차

A solution or 323.2 g of a calcium carbonate overbased alkylsalicylate (TBN 205 mgKOH/g, calcium content; 8.5 wt. %) (the calcium content of this starting material being the same as the total calcium content of the starting materials (A) and (B) in Example 1 or in each of Comparative Examples 1 and 2) and 400 g of xylene were put in a 1000-ml four-necked flask fitted with a condenser and heated to 60° C. while agitating. To this mixture was added 43.4 g of orthoboric acid, and the resulting mixture was heated up to a refluxing temperature (66° C.) under agitation and reacted for 4 hours to obtain a reaction product. The reaction product was further heated to 140° C. for 1.5 hours to distill out the reaction water and xylene. Finally the reaction product was diluted twofold with hexane and filtered to remove any residual solids present, and the hexane was distilled out to obtain a calcium borate overbased alkylsalicylate.

후처리

  1. customfitted with a condenser
  2. temperaturethe resulting mixture was heated up to a refluxing temperature (66° C.) under agitation
  3. customreacted for 4 hours
  4. customto obtain a reaction product
  5. temperatureThe reaction product was further heated to 140° C. for 1.5 hours
  6. distillationto distill out
  7. customthe reaction water and xylene
  8. filtrationfiltered
  9. customto remove any residual solids present
  10. distillationthe hexane was distilled out

출처 및 근거

ORD 기록
ord-88a06501543c4b5b93b947f3f68d505e
출처 데이터셋
uspto-grants-1995_01
특허 번호
US05380508

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