참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Malonic Acid | HCID 867 | — |
| 반응물 | Benzaldehyde, 4-hexyl- | HCID 170813 | — |
| 촉매 | Piperidine | HCID 8082 | — |
| 용매 | Pyridine | HCID 1049 | — |
| 생성물 | p-n-Hexylcinnamic acid | HCID 53878923 | — |
반응 단계
9.4 G. of p-n-hexylbenzaldehyde in 5 ml. of absolute pyridine are treated with 5.15 g. of malonic acid and 5 drops of piperidine. The mixture is then heated at 100° C. for 11 hours, subsequently poured on to cold aqueous hydrochloric acid and extracted with ether. The p-n-hexylcinnamic acid obtained after recrystallization of the crude product from hexane/ether has a melting point of 107°-109° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04066570 |
|---|
| 출처 데이터셋 | uspto-grants-1978_01 |
|---|
| ORD ID | ord-511137de192940c4a23533203fb55e02 |
|---|
| 출처 메모 | uspto-grants-1978_01 |
|---|
