Cyclopenta-1,3-diene;5-ethenylcyclopenta-1,3-diene;iron(2+) → HCID 178477623, 화합물

HRID 1856387

반응식

HRID 1856387 반응식
[CH:1]([C-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1)=[CH2:2].[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13].[C:14]([OH:17])(=[S:16])[CH3:15]>C1C=CC=CC=1>[C-:3]1([CH2:1][CH2:2][O:17][C:14](=[S:16])[CH3:15])[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13]

참가 물질

4

반응물 2

HCID 15807218Cyclopenta-1,3-diene;5-ethenylcyclopenta-1,3-diene;iron(2+)HCID 178418634HCID 178418634, 화합물

생성물 1

HCID 178477623HCID 178477623, 화합물

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

In a typical experiment 2.12g (0.01 mol) of purified vinyl ferrocene and 0.76 (0.01 mol) of thioacetic acid were dissolved in 30 ml of GC spectrophotometric quality benzene and placed in a pyrex photoreactor fitted with a fritted purging tube and reflux condenser. The solution was purged 45 minutes with helium prior and during irradiation of 1.75×1019 photon/min. from a Hanovia 100 watt type SOL high pressure quartz mercury vapor lamp. No change in the infrared bands of the mercaptans (3.9μ) and vinyl groups (6.18μ) nor any product formation could be observed by thin layer chromatography during a photolysis time of up to eight hours. It was observed that photo-decomposition of vinyl ferrocene occurred (formation of dark brown precipitate) along with protection of thioacetic acid from the ultraviolet light.

후처리

  1. customfitted with a fritted purging tube
  2. temperaturereflux condenser
  3. customThe solution was purged 45 minutes with helium
  4. customduring irradiation of 1.75×1019 photon/min
  5. customup to eight hours

출처 및 근거

ORD 기록
ord-40d3ee5830ea4665a0d3b083e37f5364
출처 데이터셋
uspto-grants-1980_08
특허 번호
US04219490

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