Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diazoethane → Ethyl 6-methoxymethyloxy-2-naphthyl-alpha-methylacetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diazoethane | HCID 70695 | — |
| 반응물 | 6-Methoxymethyloxy-2-naphthyl-alpha-methylacetic acid | HCID 20335072 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Ethyl 6-methoxymethyloxy-2-naphthyl-alpha-methylacetate | HCID 70589918 | — |
반응 단계
To a solution of 26 g. of 6-methoxymethyloxy-2-naphthyl-α-methylacetic acid and 500 ml. of diethyl ether are slowly added a solution comprising of 5.6 g. of diazoethane and 50 ml. of diethyl ether. The reaction mixture is allowed to stand for 15 minutes and then is evaporated under reduced pressure to yield ethyl 6-methoxymethyloxy-2-naphthyl-α-methylacetate. By replacing diazoethane with diazopropane in the above process, propyl 6-methoxymethyloxy-2-naphthyl-α-methylacetate is obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03998966 |
| 출처 데이터셋 | uspto-grants-1976_12 |
| ORD ID | ord-fffc5430bd27417d9921567284ad1e0e |
| 출처 메모 | uspto-grants-1976_12 |