Dinitrofluorobenzene → HCID 21999220, 화합물

HRID 1976846

반응식

HRID 1976846 반응식
F[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].C(N(CC)CC)C.[F:21][C:22]([F:48])([C:26]([F:47])([F:46])[C:27]([F:45])([F:44])[C:28]([F:43])([F:42])[C:29]([F:41])([F:40])[C:30]([F:39])([F:38])[C:31]([F:37])([F:36])[C:32]([F:35])([F:34])[F:33])[CH2:23][CH2:24][OH:25].CN(C)C(=O)C>O>[F:21][C:22]([F:48])([C:26]([F:46])([F:47])[C:27]([F:44])([F:45])[C:28]([F:42])([F:43])[C:29]([F:40])([F:41])[C:30]([F:38])([F:39])[C:31]([F:37])([F:36])[C:32]([F:35])([F:34])[F:33])[CH2:23][CH2:24][O:25][C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]

참가 물질

6

반응물 4

HCID 6264DinitrofluorobenzeneHCID 8471TriethylamineHCID 31374DimethylacetamideHCID 696191,1,2,2-Tetrahydroperfluoro-1-decanol

생성물 1

HCID 21999220HCID 21999220, 화합물수율 72%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

In a flask were charged 1-fluoro-2,4-dinitrobenzene (40.94 g, 0.22 mol), triethylamine (24.29 g, 0.24 mol), 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl alcohol (102.1 g, 0.22 mol), 220 g of N,N-dimethylacetamide and stirred at room temperature for 22 hours under a nitrogen atmosphere. The resultant etherified product was introduced into water with stirring. The solids precipitated were collected and dried at 40° C. under reduced pressure to obtain 97.22 g (yield: 72%) of 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyloxy)-1,3-dinitrobenzene as yellow crystals.

후처리

  1. stirringwith stirring
  2. customThe solids precipitated
  3. customwere collected
  4. customdried at 40° C. under reduced pressure

출처 및 근거

ORD 기록
ord-e944ad6e126d443d92bbef3fc27b561d
출처 데이터셋
uspto-grants-2001_05
특허 번호
US06228972B1

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