참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Phosphorus oxychloride | HCID 24813 | — |
| 반응물 | Phosphorus pentachloride | HCID 24819 | — |
| 반응물 | 3-Pyridinesulfonic acid | HCID 69468 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | Pyridine-3-sulfonyl chloride | HCID 3164136 | 525.5% |
반응 단계
A mixture of 3-pyridinesulfonic acid (1.0 g, 6.3 mmol), phosphorous pentachloride (1.6 g, 1.2 mmol), and phosphorous oxychloride (2.0 mL, 3.3 mmol) was combined and stirred at 100° C. for 18 h. The reaction was cooled to 25° C., diluted with CHCl3, and bubbled with HCl gas. The resulting precipitate was collected by filtration, washed with CHCl3, and dried in vacuo to yield 1.12 g of the title compound (84%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08193227B2 |
|---|
| 출처 데이터셋 | uspto-grants-2012_06 |
|---|
| ORD ID | ord-e89e0e9e749040bbaf7c12a287bc3115 |
|---|
| 출처 메모 | uspto-grants-2012_06 |
|---|
