Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diisopropyl tartrate → (2R,3R)-2-Methyl-3-propyloxiranemethanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diisopropyl tartrate | HCID 6453580 | — |
| 반응물 | (2R,3S)-2-Methyl-3-propyloxiranemethanol | HCID 10931464 | — |
| 생성물 | (2R,3R)-2-Methyl-3-propyloxiranemethanol | HCID 14959484 | 79% |
반응 단계
Using the same procedure as for the preparation of 13, (+)-DIPT and allylic alcohol 12 gave 15 in 79% yield. 1HNMR, 13C NMR IR and high resolution MS are identical to 13. [α]D=+13.9° (c=1.35, CH2,Cl2). -P NMR (10% C6D6 in benzene, 145.786 MHz) δ:132.4 (93.2%) and 133.5 (6.8%), 86.5% ee.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05426206 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-bde491f3621741dfa67e25bc60bddf0e |
| 출처 메모 | uspto-grants-1995_06 |