9,10-Bis(chloromethyl)anthracene → N~1~,N~1'~-[Anthracene-9,10-diylbis(methylene)]bis(N~2~,N~2~-dimethylethane-1,2-diamine)

HRID 2210934

반응식

HRID 2210934 반응식
Cl[CH2:2][C:3]1[C:4]2[C:9]([C:10]([CH2:17]Cl)=[C:11]3[C:16]=1[CH:15]=[CH:14][CH:13]=[CH:12]3)=[CH:8][CH:7]=[CH:6][CH:5]=2.[CH3:19][N:20]([CH3:24])[CH2:21][CH2:22][NH2:23]>O>[CH3:19][N:20]([CH3:24])[CH2:21][CH2:22][NH:23][CH2:2][C:3]1[C:4]2[C:9]([C:10]([CH2:17][NH:23][CH2:22][CH2:21][N:20]([CH3:24])[CH3:19])=[C:11]3[C:16]=1[CH:15]=[CH:14][CH:13]=[CH:12]3)=[CH:8][CH:7]=[CH:6][CH:5]=2

참가 물질

4

반응물 2

HCID 252199,10-Bis(chloromethyl)anthraceneHCID 66053N,N-Dimethylethylenediamine

생성물 1

HCID 60242N~1~,N~1'~-[Anthracene-9,10-diylbis(methylene)]bis(N~2~,N~2~-dimethylethane-1,2-diamine)수율 36.7%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

1.0 g (0.0036 mol) of 9,10-dichloromethylanthracene (0.0036 mol) is refluxed for 20 minutes with 15 g of 2-dimethylaminoethylamine. The reaction mixture is added to water and the precipitate collected by filtration. The dried solid is then recrystallised from ethyl acetate to yield 0.5 g of the title compound as yellow crystals, m.p. 58°-60° C.; λmax (distilled water) (E/cm/M) 248 nm (51760), 372 nm (9030), 392 nm (8305).

후처리

  1. filtrationthe precipitate collected by filtration
  2. customThe dried solid is then recrystallised from ethyl acetate

출처 및 근거

ORD 기록
ord-1627f4ee3e49405582af87ecf97f6654
출처 데이터셋
uspto-grants-1995_10
특허 번호
US05461078

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