Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethyl Ether → 4-Methyl-3-methylene-1-isopropenyl cyclohexane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | (+)-Dihydrocarvone | HCID 22227 | — |
| 생성물 | 4-Methyl-3-methylene-1-isopropenyl cyclohexane | HCID 14766002 | 95% |
반응 단계
BDAM (2.60 grams) was combined with ether (2 milliliters) and TMAL (1.0 milliliter) as described in Example 4, after which 1.50 grams of (+) dihydrocarvone were added. As in Example 4, a noticeably exotherm was observed. After 3 hours of stirring at room temperature, the reaction mixture was hydrolyzed as in Example 1. After the usual work up and column separation, 1.40 grams of 4-methyl-3-methylene-1-isopropenyl cyclohexane were isolated (95% yield).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04788367 |
| 출처 데이터셋 | uspto-grants-1988_11 |
| ORD ID | ord-d43c1a8d14f64c64a8352d188aeb8eea |
| 출처 메모 | uspto-grants-1988_11 |