Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → Cyclododecane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Cyclododecane | HCID 9268 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 반응물 | Cumen hydroperoxide | HCID 53627471 | — |
| 생성물 | Cyclododecane | HCID 9268 | — |
| 생성물 | Cyclododecanone | HCID 13246 | — |
| 생성물 | Cyclododecanol | HCID 15595 | — |
반응 단계
2 mmol of N-hydroxyphthalimide and 4 mmol of cumene hydroperoxide are added at a temperature of 130° C. to 200 mmol of cyclododecane in a round-bottomed flask having an attached reflux condenser. Oxygen at approximately 15 l/h is passed through the reaction mixture for 8 hours at said temperature. Cyclododecanol is obtained at a selectivity of 17% and cyclododecanone at a selectivity of 43%, at a cyclododecane conversion rate of 49%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06852893B2 |
| 출처 데이터셋 | uspto-grants-2005_02 |
| ORD ID | ord-7ff214af37b644dcb39ffcdfde6309f3 |
| 출처 메모 | uspto-grants-2005_02 |